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In reality,

In reality, cats possess the ability to turn themselves right side up in mid-air if they should fall upside-down, known as the cat righting reflex. This enables them to land on their feet if dropped from sufficient height, about 30 cm (12 in).(17)


Toast, being an inanimate object, lacks both the ability and the desire to right itself. Toast typically lands on the floor butter-side-down due to the manner in which it is typically dropped from a table. As the toast falls from the table, it rotates. Given the typical speed of rotation for a slice of toast as it falls from the table and the typical height of a table, a slice of toast that began butter-side-up on the table will land butter-side-down on the floor in 81% of cases.(18)


Cats can weigh between 2.8 kg (6.2 pounds) and 6.1 kg (13.4 pounds).(19) A 25 g (0.9 oz) slice of bread(20) will have a negligible effect on the movement of the much larger cat.